Solid state interconversion of cages and coordination networks via conformational change of a semi-rigid ligand.
نویسندگان
چکیده
The reaction of silver(i) perchlorate with the semi-rigid ligand 1,4-bis((3,5-dimethylisoxazol-4-yl)methyl)benzene (bisox) in methanol gives a triply-interpenetrated sheet structure, but a structure containing both interpenetrated sheets and Ag(2)(bisox)(3) cages is formed on recrystallisation from acetonitrile-diethyl ether. Rearrangement of the cages into sheets occurs on heating under vacuum, a process which involves a solid state change in conformation of the bisox ligands.
منابع مشابه
Theoretical and Conformational Study of Pinched-cone Interconversion in monosubstituted tri-methylsilyle ethynyl Derivative of Calix[4]arene
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عنوان ژورنال:
- Chemical communications
دوره 46 28 شماره
صفحات -
تاریخ انتشار 2010